1,​1,​1-​Trifluoro-​N-​[(11bR)​-​4-​oxido-​2,​6-​bis(triphenylsilyl)​dinaphtho[2,​1-​d:1',​2'-​f]​[1,​3,​2]​dioxaphosphepin-​4-​yl]​methanesulfonamide - CAS 1099596-63-0

Inquiry
As a strong chiral Brønsted acid, 1,​1,​1-​Trifluoro-​N-​[(11bR)​-​4-​oxido-​2,​6-​bis(triphenylsilyl)​dinaphtho[2,​1-​d:1',​2'-​f]​[1,​3,​2]​dioxaphosphepin-​4-​yl]​methanesulfonamide is a chiral N-triflyl phosphoramides organocatalysts for enantioselective synthesis.

Product Information

Canonical SMILES
O=S(C(F)(F)F)(NP1(OC2=C([Si](C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5)C=C6C=CC=CC6=[C@]2[C@]7=C8C=CC=CC8=CC([Si](C9=CC=CC=C9)(C%10=CC=CC=C%10)C%11=CC=CC=C%11)=C7O1)=O)=O
Storage
Inert atmosphere. Keep cold.
Density
1.4±0.1 g/mL

Safety Information

Signal Word
Warning
Precautionary Statement
P261 - P280 - P301+P312 - P302+P352 - P305+P351+P338
Hazard Statements
H302 - H315 - H319 - H335
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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(S)-1,1,1-Trifluoro-N-(4-oxido-7a,8,9,10,11,11a,12,13,14,15-decahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)methanesulfonamide (CAS: 2304917-54-0)
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(S)-N-(2,6-Di(naphthalen-1-yl)-4-oxido-7a,8,9,10,11,11a,12,13,14,15-decahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-1,1,1-trifluoromethanesulfonamide
1,​1,​1-Trifluoro-​N-​[(11bR)​-​4-​oxido-​2,​6-​diphenyldinaphtho[2,​1-​d:1',​2'-​f]​[1,​3,​2]​dioxaphosphepin-​4-​yl]methanesulfonamide (CAS: 1010799-98-0)
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