1,​1,​1-​Trifluoro-​N-​[(11bS)​-​8,​9,​10,​11,​12,​13,​14,​15-​octahydro-​4-​oxido-​2,​6-​diphenyl-dinaphtho[2,​1-​d:1',​2'-​f]​[1,​3,​2]​dioxaphosphepin-​4-​yl]​methanesulfonamide - CAS 1773513-29-3

Inquiry
As a strong chiral Brønsted acid, 1,​1,​1-​Trifluoro-​N-​[(11bS)​-​8,​9,​10,​11,​12,​13,​14,​15-​octahydro-​4-​oxido-​2,​6-​diphenyl-dinaphtho[2,​1-​d:1',​2'-​f]​[1,​3,​2]​dioxaphosphepin-​4-​yl]​methanesulfonamide is a chiral N-triflyl phosphoramides organocatalysts for enantioselective synthesis.

Product Information

Canonical SMILES
O=P1(OC(C(C2=CC=CC=C2)=CC3=C4CCCC3)=[C@]4[C@@]5=C6CCCCC6=CC(C7=CC=CC=C7)=C5O1)NS(=O)(C(F)(F)F)=O
Storage
Inert atmosphere. Keep cold.
Boiling Point
749.4 + / - 70.0 °C / 760 mmHg
Density
1.47±0.1 g/mL

Safety Information

Signal Word
Warning
Precautionary Statement
P261 - P280 - P301+P312 - P302+P352 - P305+P351+P338
Hazard Statements
H302 - H315 - H319 - H335
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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Related Products

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1,​1,​1-Trifluoro-​N-​[(11bR)​-​4-​oxido-​2,​6-​diphenyldinaphtho[2,​1-​d:1',​2'-​f]​[1,​3,​2]​dioxaphosphepin-​4-​yl]methanesulfonamide (CAS: 1010799-98-0)
(R)-N-(2,6-Bis(3,5-dimethylphenyl)-4-oxido-7a,8,9,10,11,11a,12,13,14,15-decahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-1,1,1-trifluoromethanesulfonamide
1,​1,​1-​Trifluoro-​N-​[(6S)​-​6-​oxido-​4,​8-bis(3,5-dimethylphenyl)dibenzo[d,f][1,3,2]dioxaphosphepin-​6-​yl]​methanesulfonamide
(S)-N-(2,6-Bis(4-(tert-butyl)phenyl)-4-oxido-7a,8,9,10,11,11a,12,13,14,15-decahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-1,1,1-trifluoromethanesulfonamide (CAS: 1643958-21-7)
1,1,1-Trifluoro-N-(3aS,8aS)-4,4,8,8-tetrakis(3,5-di-tert-butylphenyl)-2,2-bis(4-fluorophenyl)-6-hydroxy-tetrahydro-6-oxide-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine-6-yl)methanesulfonamide
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