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1,2-Bis[(2R,5R)-2,5-dimethylphospholano]-3,3,4,4-tetrafluoro-1-cyclobutene(1,5-cyclooctadiene)rhodium(I) ) tetrafluorob

1,2-Bis[(2R,5R)-2,5-dimethylphospholano]-3,3,4,4-tetrafluoro-1-cyclobutene(1,5-cyclooctadiene)rhodium(I) ) tetrafluorob - CAS 910048-20-3

1,2-Bis[(2R,5R)-2,5-dimethylphospholano]-3,3,4,4-tetrafluoro-1-cyclobutene(1,5-cyclooctadiene)rhodium(I) ) tetrafluorob is a chiral Ligand that has been intensively applied in asymmetric reactions by modifying the reactivity and selectivity of the metal center.

Catalog Number

910048-20-3

CAS

910048-20-3

IUPAC Name

(1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]-3,3,4,4-tetrafluorocyclobuten-1-yl]-2,5-dimethylphospholane;rhodium;tetrafluoroborate

Synonyms

1,2-Bis[(2R,5R)-2,5-dimethyl-phospholanyl]3,3,4,4-tetrafluoro-1-cyclobutene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Molecular Weight

652.19

Molecular Formula

C24H36BF8P2Rh

Product Information

Canonical SMILES

[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C[C@@H]2CC[C@@H](C)P2C3=C(P4[C@H](C)CC[C@H]4C)C(F)(F)C3(F)F

InChI

InChI=1S/C16H24F4P2.C8H12.BF4.Rh/c1-9-5-6-10(2)21(9)13-14(16(19,20)15(13,17)18)22-11(3)7-8-12(22)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h9-12H,5-8H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t9-,10-,11-,12-;;;/m1.../s1

InChI Key

NTIPVSFGRVAMKI-HEEUKTGESA-N

Purity

95%

MDL

MFCD10567388

WGK Germany

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

Mass