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Chiral Phosphine Ligands
1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate

1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate - CAS 187682-63-9

1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

187682-63-9

CAS

187682-63-9

IUPAC Name

(1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane;rhodium;trifluoromethanesulfonate

Molecular Weight

666.52

Molecular Formula

C27H40F3O3P2RhS

Product Information

Canonical SMILES

[Rh+].[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1.C[C@@H]2CC[C@@H](C)P2c3ccccc3P4[C@H](C)CC[C@H]4C

InChI

InChI=1S/C18H28P2.C8H12.CHF3O3S.Rh/c1-13-9-10-14(2)19(13)17-7-5-6-8-18(17)20-15(3)11-12-16(20)4;1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h5-8,13-16H,9-12H2,1-4H3;1-2,7-8H,3-6H2;(H,5,6,7);/p-1/b;2-1-,8-7-;;/t13-,14-,15-,16-;;;/m1.../s1

InChI Key

HFNBCEIZBZROGX-MYDVBLLJSA-M

Purity

≥97%

MDL

MFCD00269862

WGK Germany