Home
Chiral Compounds
Chiral Ligands
Chiral Nitrogen Ligands
1-Naphthalenecarboxamide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-

1-Naphthalenecarboxamide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)- - CAS 174810-09-4

Name: 1-Naphthalenecarboxamide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-
Brand: BOC Sciences
Rating: 5 (1 reviews)

Inquiry

1-Naphthalenecarboxamide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)- is a chiral nitrogen ligand for enantioselective synthesis.

Catalog Number

174810-09-4

CAS

174810-09-4

IUPAC Name

2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide

Synonyms

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL); (R,R)-TROST LIGAND(NAPHTHYL); (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(R,R)-DACH-NaphthylTrostLigand; (R,R)-DACH-naphthyl Trost ligan

Molecular Weight

790.87

Molecular Formula

C52H44 N2 O2 P2

Product Information

Canonical SMILES

O=C(N[C@H]1[C@H](NC(C2=C3C=CC=CC3=CC=C2P(C4=CC=CC=C4)C5=CC=CC=C5)=O)CCCC1)C6=C7C=CC=CC7=CC=C6P(C8=CC=CC=C8)C9=CC=CC=C9

InChI

InChI=1S/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m1/s1

InChI Key

VXFKMKXTPXVEMU-AWSIMMLFSA-N

Purity

95%

MDL

MFCD02684551

Physical State

Solid

Storage

Inert atmosphere. Keep cold.

Melting Point

224-231 °C

Optical Activity

+69.0°( c = 1 in methanol)

WGK Germany

Safety Information

Signal Word

Warning

Precautionary Statement

P261 - P280 - P301 - P312 - P302 - P352 - P305 - P351 - P338

Hazard Statements

H302 - H315 - H319 - H335

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

Mass

Concentration

Volume

Molecular Weight *

Calculate

The dilution calculator equation

Concentration _(start) × Volume _(start) = Concentration _(final) × Volume _(final)

This equation is commonly abbreviated as: C₁V₁ = C₂V₂

Concentration _(start)

Volume _(start)

Concentration _(final)

Volume _(final)

Calculate

1-Naphthalenecarboxamide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)- - CAS 174810-09-4

Product Information

Safety Information

Related Products