(11bR)-2,6-Bis(4-chlorophenyl)-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin - CAS 915038-16-3

Inquiry
(11bR)-2,6-Bis(4-chlorophenyl)-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin is a chiral phosphoric acid catalyst for a variety of enantioselective transformations, especially for carbon-carbon and carbon-heteroatom bond-forming reactions.

Product Information

Canonical SMILES
O=P1(OC2=C(C3=C(CCCC3)C=C2C4=CC=C(Cl)C=C4)C5=C(C(C6=CC=C(Cl)C=C6)=CC7=C5CCCC7)O1)O
Storage
Inert atmosphere. Keep cold.
Boiling Point
770.9±70.0 °C / 760 mmHg
Melting Point
252-254 °C
Density
1.46±0.1 g/mL
Optical Activity
-137 ° (c =0.2 in chloroform)

Safety Information

Signal Word
Warning
Precautionary Statement
P264 - P280 - P302+P352 - P332+P313 - P362+P364
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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(11bR)-4-Hydroxy-2,6-bis(5'-phenyl[1,1':3',1''-terphenyl]-2'-yl)-4-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepinoxide
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(11bR)​-8,​9,​10,​11,​12,​13,​14,​15-​Octahydro-​4-​hydroxy-​2,​6-​bis(3,5-di-tert-butyl-4-methoxyphenyl)​-4-​oxide-dinaphtho[2,​1-​d:1',​2'-​f]​[1,​3,​2]​dioxaphosphepin
(11aR)-3,7-Bis[3,5-bis(tert-butyl)-4-methoxyphenyl]-10,11,12,13-tetrahydro-10,10,13,13-tetramethyl-5-hydroxy[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin
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