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Chiral Phosphoric Acids
(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis(2,4,6-trimethylphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis(2,4,6-trimethylphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin - CAS 1011465-23-8

(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis(2,4,6-trimethylphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin is a chiral phosphoric acid catalyst for a variety of enantioselective transformations, especially for carbon-carbon and carbon-heteroatom bond-forming reactions.

Catalog Number

1011465-23-8

CAS

1011465-23-8

Molecular Weight

592.7

Molecular Formula

C38H41O4P

Product Information

Canonical SMILES

CC1=C(C2=C(OP(OC3=C(C4=C(C)C=C(C)C=C4C)C=C5CCCCC5=C36)(O)=O)C6=C7CCCCC7=C2)C(C)=CC(C)=C1

Storage

Inert atmosphere. Keep cold.

Boiling Point

729.6±70.0 °C / 760 mmHg

Melting Point

174-176 °C

Density

1.26±0.1 g/mL

Optical Activity

-181.3 °( c =0.35 in chloroform)

Safety Information

Signal Word

Warning

Precautionary Statement

P264 - P280 - P302+P352 - P332+P313 - P362+P364

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Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration _(start) × Volume _(start) = Concentration _(final) × Volume _(final)

This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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(11bR)​-8,​9,​10,​11,​12,​13,​14,​15-​Octahydro-​4-​hydroxy-​2,​6-​bis(2,​4,​6-​trimethylphenyl)​-4-​oxide-dinaphtho[2,​1-​d:1',​2'-​f]​[1,​3,​2]​dioxaphosphepin - CAS 1011465-23-8

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Related Products

(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-bis(2,4,6-trimethylphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin - CAS 1011465-23-8