(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-9-phenanthrenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin - CAS 934201-93-1

Inquiry
(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-9-phenanthrenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin is a chiral phosphoric acid catalyst for a variety of enantioselective transformations, especially for carbon-carbon and carbon-heteroatom bond-forming reactions.

Product Information

Canonical SMILES
O=P(O)(O)O.C1(C2=C3CCCCC3=CC(C4=CC5=CC=CC=C5C6=CC=CC=C64)=C2)=C7CCCCC7=CC(C8=CC9=CC=CC=C9C%10=CC=CC=C%108)=C1
Storage
Inert atmosphere. Keep cold.
Melting Point
252-255 °C
Density
1.4±0.1 g/mL
Optical Activity
-160.1 ° (c = 0.5 in chloroform)

Safety Information

Signal Word
Warning
Precautionary Statement
P264 - P280 - P302 - P352 - P332 - P313 - P362 - P364
Hazard Statements
H315
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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(3aR,8aR)-4,4,8,8-Tetra-9-phenanthrenel-tetrahydro-6-hydroxy-2,2-dimethyl-6-oxide-1,3-dioxolo[4,5-e][1,3,2]dioxaphosphepin
(S)-4-Hydroxy-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide (CAS: 1193697-61-8)
(11bR)​-8,​9,​10,​11,​12,​13,​14,​15-​Octahydro-​4-​hydroxy-​2,​6-​bis(3,5-di-tert-butyl-4-methoxyphenyl)​-4-​oxide-dinaphtho[2,​1-​d:1',​2'-​f]​[1,​3,​2]​dioxaphosphepin
(11aR)-3,7-Bis[3,5-bis(tert-butyl)-4-methoxyphenyl]-10,11,12,13-tetrahydro-10,10,13,13-tetramethyl-5-hydroxy[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin
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