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Chiral Compounds
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Chiral Phosphine Ligands
(1R,aR)-3-Diphenylphosphino-2-(4-bis(3,5-dimethylphenyl)phosphino-2,5-dimethyl-3-thienyl)-1,7,7-trimethylbicyclo[2.2.1]hept-2-ene

(1R,aR)-3-Diphenylphosphino-2-(4-bis(3,5-dimethylphenyl)phosphino-2,5-dimethyl-3-thienyl)-1,7,7-trimethylbicyclo[2.2.1]hept-2-ene - CAS 868851-50-7

(1R,aR)-3-Diphenylphosphino-2-(4-bis(3,5-dimethylphenyl)phosphino-2,5-dimethyl-3-thienyl)-1,7,7-trimethylbicyclo[2.2.1]hept-2-ene is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

868851-50-7

CAS

868851-50-7

IUPAC Name

bis(3,5-dimethylphenyl)-[4-(3-diphenylphosphanyl-1,7,7-trimethyl-2-bicyclo[2.2.1]hept-2-enyl)-2,5-dimethylthiophen-3-yl]phosphane

Synonyms

3-[Bis(3,5-dimethylphenyl)phosphanyl]-4-[(1R,4S)-3-diphenylphosphanyl-1,7,7-trimethylbicyclo[2.2.1]hept-2-en-2-yl]-2,5-dimethylthiophene, catASium

Molecular Weight

670.86

Molecular Formula

C44H48P2S

Product Information

Canonical SMILES

CC1=CC(C)=CC(P(C2=CC(C)=CC(C)=C2)C3=C(C)SC(C)=C3C4=C([C@@]([H])(CC[C@@]45C)C5(C)C)P(C6=CC=CC=C6)C7=CC=CC=C7)=C1

InChI

InChI=1S/C44H48P2S/c1-28-22-29(2)25-36(24-28)46(37-26-30(3)23-31(4)27-37)41-33(6)47-32(5)39(41)40-42(38-20-21-44(40,9)43(38,7)8)45(34-16-12-10-13-17-34)35-18-14-11-15-19-35/h10-19,22-27,38H,20-21H2,1-9H3

InChI Key

BTWWTSUDALLJMO-UHFFFAOYSA-N

MDL

MFCD10566967

Physical State

Solid

Appearance

Powder

Storage

Inert atmosphere. Keep cold.

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)