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3,3'-Bipyridine,4,4'-bis(diphenylphosphino)-2,2',6,6'-tetramethoxy-, (3S)-

3,3'-Bipyridine,4,4'-bis(diphenylphosphino)-2,2',6,6'-tetramethoxy-, (3S)- - CAS 362524-23-0

3,3'-Bipyridine,4,4'-bis(diphenylphosphino)-2,2',6,6'-tetramethoxy-, (3S)- is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

362524-23-0

CAS

362524-23-0

IUPAC Name

[3-(4-diphenylphosphanyl-2,6-dimethoxypyridin-3-yl)-2,6-dimethoxypyridin-4-yl]-diphenylphosphane

Synonyms

CTH-(R)-P-PHOS; CTH-(S)-P-PHOS; (S)-(-)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DIPHENYLPHOSPHINO)-3,3'-BIPYRIDINE; (S)-(-)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DIPHENYLPHOSPHINO)-3,3-BIPYRIDINE; (R)-P-PHOS; (S)-P-PHOS; (R)-(-)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DIPHENYLPHOSP

Molecular Weight

644.64

Molecular Formula

C38H34 N2 O4 P2

Product Information

Canonical SMILES

COC1=CC(P(C2=CC=CC=C2)C3=CC=CC=C3)=C(C4=C(P(C5=CC=CC=C5)C6=CC=CC=C6)C=C(OC)N=C4OC)C(OC)=N1

InChI

InChI=1S/C38H34N2O4P2/c1-41-33-25-31(45(27-17-9-5-10-18-27)28-19-11-6-12-20-28)35(37(39-33)43-3)36-32(26-34(42-2)40-38(36)44-4)46(29-21-13-7-14-22-29)30-23-15-8-16-24-30/h5-26H,1-4H3

InChI Key

JZOSBBLJKXSBBN-UHFFFAOYSA-N

Purity

97%

MDL

MFCD04038734

Physical State

Solid

Appearance

White solid

Storage

Inert atmosphere. Keep cold.

Optical Activity

-98°( c = 1 in chloroform)

WGK Germany

Safety Information

Signal Word

Warning

Precautionary Statement

P261 - P280 - P301 - P312 - P302 - P352 - P305 - P351 - P338

Hazard Statements

H302 - H315 - H319 - H335

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration _(start) × Volume _(start) = Concentration _(final) × Volume _(final)

This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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3,3'-Bipyridine,4,4'-bis(diphenylphosphino)-2,2',6,6'-tetramethoxy-, (3S)- - CAS 362524-23-0

Product Information

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