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Chiral Compounds
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Chiral Phosphine Ligands
(3aR,8aR)-()-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine

(3aR,8aR)-()-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine - CAS 213843-90-4

(3aR,8aR)-()-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

213843-90-4

CAS

213843-90-4

IUPAC Name

(3aR,8aR)-N,N,2,2-tetramethyl-4,4,8,8-tetraphenyl-3a,8a-dihydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-amine

Application

(3aR,8aR)-(−)-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine is Phosphoramidite ligand employe

Molecular Weight

539.60

Molecular Formula

C33H34NO4P

Product Information

Canonical SMILES

CN(P1OC(C2=CC=CC=C2)(C3=CC=CC=C3)[C@@]4([H])[C@](OC(C)(O4)C)([H])C(C5=CC=CC=C5)(C6=CC=CC=C6)O1)C

InChI

InChI=1S/C33H34NO4P/c1-31(2)35-29-30(36-31)33(27-21-13-7-14-22-27,28-23-15-8-16-24-28)38-39(34(3)4)37-32(29,25-17-9-5-10-18-25)26-19-11-6-12-20-26/h5-24,29-30H,1-4H3/t29-,30-/m1/s1

InChI Key

DRPNADVMTMEWQY-LOYHVIPDSA-N

Purity

96%

MDL

MFCD04117685

Physical State

Solid

Storage

Inert atmosphere. Keep cold.

Boiling Point

569.804 °C / 760 mmHg

Melting Point

218-221 °C

WGK Germany

Safety Information

Signal Word

Warning

Precautionary Statement

P280 - P305 - P351 - P338

Hazard Statements

H317 - H319

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration _(start) × Volume _(start) = Concentration _(final) × Volume _(final)

This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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(3aR,8aR)-()-(2,2-Dimethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)dimethylamine - CAS 213843-90-4

Product Information

Safety Information

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