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Chiral Compounds
Chiral Ligands
Chiral Phosphine Ligands
Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'- octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-H8-binap)]Cl

Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'- octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-H8-binap)]Cl - CAS 944451-26-7

Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'- octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-H8-binap)]Cl is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

944451-26-7

CAS

944451-26-7

IUPAC Name

dichlororuthenium;[1-(2-diphenylphosphanyl-5,6,7,8-tetrahydronaphthalen-1-yl)-5,6,7,8-tetrahydronaphthalen-2-yl]-diphenylphosphane;1-methyl-4-propan-2-ylbenzene

Synonyms

Chloro[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride

Molecular Weight

936.93

Molecular Formula

[C54H54ClP2Ru]+Cl-

Product Information

Canonical SMILES

[Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.C2CCc3c(C2)ccc(P(c4ccccc4)c5ccccc5)c3-c6c7CCCCc7ccc6P(c8ccccc8)c9ccccc9

InChI

InChI=1S/C44H40P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-12,19-26,29-32H,13-18,27-28H2;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChI Key

RDVYAXZMACLMGN-UHFFFAOYSA-L

Physical State

Solid

Appearance

Powder

Storage

Keep cold.

WGK Germany

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

Mass