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Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II)

Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) - CAS 374067-50-2

Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

374067-50-2

CAS

374067-50-2

IUPAC Name

acetic acid;[1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane;ruthenium

Synonyms

Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II); (R)-Ru(OAc)2(DM-BINAP); Diacetato[(R)-2,2μ-bis[di(3,5-xylyl)phosphino]-1,1μ-binaphtyl]ruthenium(II)

Molecular Formula

C56H54O4P2Ru

Product Information

Canonical SMILES

CC1=CC(=CC(=C1)P(C2=C(C3=CC=CC=C3C=C2)C4=C(C=CC5=CC=CC=C54)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.CC(=O)O.CC(=O)O.[Ru]

InChI

InChI=1S/C52H48P2.2C2H4O2.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;2*1-2(3)4;/h9-32H,1-8H3;2*1H3,(H,3,4);

InChI Key

HDUAMHMUQGCXCT-UHFFFAOYSA-N

Purity

95%

MDL

MFCD09753022

Physical State

Solid

Appearance

Tan to dark brown powder

Storage

Sealed in dry. Keep cold.