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Diacetato{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II)

Diacetato{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) - CAS 374067-49-9

Diacetato{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

374067-49-9

CAS

374067-49-9

IUPAC Name

acetic acid;[1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane;ruthenium

Synonyms

Diacetato{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II); (S)-Ru(OAc)2(DM-BINAP)

Molecular Weight

954.057

Molecular Formula

C52H48P2.C4H6O4Ru

Product Information

Canonical SMILES

CC(=O)O[Ru]OC(C)=O.Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7cc(C)cc(C)c7)c8cc(C)cc(C)c8

InChI

InChI=1S/C52H48P2.2C2H4O2.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;2*1-2(3)4;/h9-32H,1-8H3;2*1H3,(H,3,4);

InChI Key

HDUAMHMUQGCXCT-UHFFFAOYSA-N

MDL

MFCD09753022

Physical State

Solid

Appearance

Tan to dark brown powder

Storage

Sealed in dry. Keep cold.

WGK Germany

The molarity calculator equation