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Chiral Phosphine Ligands
Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin,10,11,12,13-tetrahydro-5-phenoxy-, (11aR)-

Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin,10,11,12,13-tetrahydro-5-phenoxy-, (11aR)- - CAS 656233-53-3

Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin,10,11,12,13-tetrahydro-5-phenoxy-, (11aR)- is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

656233-53-3

CAS

656233-53-3

IUPAC Name

12-phenoxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine

Synonyms

(11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY; (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY; (R)-SHIP; (S)-SHIP; PHENYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE; PHEN

Molecular Weight

374.37

Molecular Formula

C23H19 O3 P

Product Information

Canonical SMILES

C1(OP2OC3=C4C(CCC45C6=C(CC5)C=CC=C6O2)=CC=C3)=CC=CC=C1

InChI

InChI=1S/C23H19O3P/c1-2-8-18(9-3-1)24-27-25-19-10-4-6-16-12-14-23(21(16)19)15-13-17-7-5-11-20(26-27)22(17)23/h1-11H,12-15H2

InChI Key

JVANYVSBBJFGMW-UHFFFAOYSA-N

Physical State

Solid

Appearance

Powder

Storage

Inert atmosphere. Keep cold.

Boiling Point

454.8±45.0 °C / 760 mmHg

Safety Information

Signal Word

Warning

Precautionary Statement

P261 - P305 - P351 - P338

Hazard Statements

H302 - H315 - H319 - H335

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration _(start) × Volume _(start) = Concentration _(final) × Volume _(final)

This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin,10,11,12,13-tetrahydro-5-phenoxy-, (11aR)- - CAS 656233-53-3

Product Information

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