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Chiral Phosphine Ligands
Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-5, 5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH 2 Me 2 ][{RuCl((S)-H 8 -binap)} 2 (μ-Cl) 3 ]

Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-5, 5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH 2 Me 2 ][{RuCl((S)-H 8 -binap)} 2 (μ-Cl) 3 ] - CAS 944451-12-1

Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-5, 5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH 2 Me 2 ][{RuCl((S)-H 8 -binap)} 2 (μ-Cl) 3 ] is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

944451-12-1

CAS

944451-12-1

IUPAC Name

[1-(2-diphenylphosphanyl-5,6,7,8-tetrahydronaphthalen-1-yl)-5,6,7,8-tetrahydronaphthalen-2-yl]-diphenylphosphane;N-methylmethanamine;ruthenium;trichloronioruthenium(1-);chloride;hydrochloride

Synonyms

Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)

Molecular Weight

1685.96

Molecular Formula

(CH3)2NH2+[C88H80Cl5P4Ru2]-

Product Information

Canonical SMILES

CNC.C1CCC2=C(C1)C=CC(=C2C3=C(C=CC4=C3CCCC4)P(C5=CC=CC=C5)C6=CC=CC=C6)P(C7=CC=CC=C7)C8=CC=CC=C8.C1CCC2=C(C1)C=CC(=C2C3=C(C=CC4=C3CCCC4)P(C5=CC=CC=C5)C6=CC=CC=C6)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl.[Cl-].[ClH+][Ru-]([ClH+])[ClH+].[Ru]

InChI

InChI=1S/2C44H40P2.C2H7N.5ClH.2Ru/c2*1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-3-2;;;;;;;/h2*1-12,19-26,29-32H,13-18,27-28H2;3H,1-2H3;5*1H;;/q;;;;;;;;;+2/p-1

InChI Key

GTOHIFITHYJFSD-UHFFFAOYSA-M

MDL

MFCD09753036

Storage

Keep cold.

WGK Germany

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

Mass