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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl] diruthenate(II)

Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl] diruthenate(II) - CAS 199684-47-4

Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl] diruthenate(II) is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

199684-47-4

CAS

199684-47-4

IUPAC Name

[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;N-methylmethanamine;ruthenium;trichloronioruthenium(1-);chloride;hydrochloride

Synonyms

Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II); (R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2]; Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(II)

Molecular Formula

(CH3)2NH2+[C88H64Cl5P4Ru2]-

Product Information

Canonical SMILES

CNC.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl.[Cl-].[ClH+][Ru-]([ClH+])[ClH+].[Ru]

InChI

InChI=1S/2C44H32P2.C2H7N.5ClH.2Ru/c2*1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-3-2;;;;;;;/h2*1-32H;3H,1-2H3;5*1H;;/q;;;;;;;;;+2/p-1

InChI Key

NVDGOPZSESFSJS-UHFFFAOYSA-M

Purity

95%

MDL

MFCD09753033

Physical State

Solid

Appearance

Powder or Crystals

Storage

Keep in dark place. Inert atmosphere. Keep cold.

WGK Germany

Safety Information

Signal Word

Warning

Precautionary Statement

P501 - P260 - P314

Hazard Statements

H373

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This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl] diruthenate(II) - CAS 199684-47-4

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