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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II)

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) - CAS 309735-86-2

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

309735-86-2

CAS

309735-86-2

IUPAC Name

[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;dichlororuthenium;N-methylmethanamine;hydrochloride

Synonyms

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II); (S)-[(RuCl (T-BINAP))2(μ-Cl)3[NH2Me2]; Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(di-p-tolylphosphino)-1,1μ-binaphthyl]diruth

Molecular Weight

1783.08

Molecular Formula

2C48H40P2.C2H7N.Cl.Cl3Ru2.ClH

Product Information

Canonical SMILES

CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C.CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C.CNC.Cl.[Cl-].[ClH+][Ru-]([ClH+])[ClH+].[Ru]

InChI

InChI=1S/2C48H40P2.C2H7N.5ClH.2Ru/c2*1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;1-3-2;;;;;;;/h2*5-32H,1-4H3;3H,1-2H3;5*1H;;/q;;;;;;;;;+2/p-1

InChI Key

BKLYSQLZSZMPAP-UHFFFAOYSA-M

Purity

95%

MDL

MFCD09753034

Physical State

Solid

Appearance

Powder or Crystals

Storage

Keep in dark place. Inert atmosphere. Keep cold.

Hazard Class

4.1

WGK Germany

Packing Groups

III

Safety Information

Signal Word

Danger

Precautionary Statement

P501 - P202 - P201 - P280 - P308+P313 - P405

Hazard Statements

H228

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Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration _(start) × Volume _(start) = Concentration _(final) × Volume _(final)

This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) - CAS 309735-86-2

Product Information

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