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Chiral N-Triflyl Phosphoramides
N-[(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-8,9,10,11,12,13,14,15-octahydro-4-oxido-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide

N-[(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-8,9,10,11,12,13,14,15-octahydro-4-oxido-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide - CAS 1261302-64-0

As a strong chiral Brønsted acid, N-[(11bR)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-8,9,10,11,12,13,14,15-octahydro-4-oxido-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide is a chiral N-triflyl phosphoramides organocatalysts for enantioselective synthesis.

Catalog Number

1261302-64-0

CAS

1261302-64-0

Molecular Weight

911.6

Molecular Formula

C37H25F15NO5PS

Product Information

Canonical SMILES

FC(F)(F)S(NP1(OC2=C(C3=C(CCCC3)C=C2C4=CC(C(F)(F)F)=CC(C(F)(F)F)=C4)C5=C(C(C6=CC(C(F)(F)F)=CC(C(F)(F)F)=C6)=CC7=C5CCCC7)O1)=O)(=O)=O

Storage

Inert atmosphere. Keep cold.

Boiling Point

735.0±70.0 °C / 760 mmHg

Melting Point

188-192 °C

Density

1±0.1 g/mL

Optical Activity

-134.9 °( c =0.5 in chloroform)

Safety Information

Signal Word

Warning

Precautionary Statement

P261 - P280 - P301+P312 - P302+P352 - P305+P351+P338

Hazard Statements

H302 - H315 - H319 - H335

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This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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