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Chiral Phosphine Ligands
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) - CAS 490023-37-5

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

490023-37-5

CAS

490023-37-5

IUPAC Name

N-benzyl-N-methyl-12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-amine

Synonyms

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE; (S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)METHYLAMINE; (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS

Molecular Weight

435.45

Molecular Formula

C28H22NO2P

Product Information

Canonical SMILES

CN(CC1=CC=CC=C1)P2OC3=CC=C4C=CC=CC4=C3C5=C6C=CC=CC6=CC=C5O2

InChI

InChI=1S/C28H22NO2P/c1-29(19-20-9-3-2-4-10-20)32-30-25-17-15-21-11-5-7-13-23(21)27(25)28-24-14-8-6-12-22(24)16-18-26(28)31-32/h2-18H,19H2,1H3

InChI Key

OHGGHRJGBXAKKY-UHFFFAOYSA-N

Purity

95%

MDL

MFCD04117686

Storage

Inert atmosphere. Keep cold.

Boiling Point

635.418°C at 760 mmHg

Melting Point

155-159°C

WGK Germany

Safety Information

Signal Word

Warning

Precautionary Statement

P261 - P305 - P351 - P338

Hazard Statements

H302 - H315 - H319 - H335

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Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

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This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS) - CAS 490023-37-5

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