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Chiral Phosphine Ligands
(R)-1-{(RP)-2-[2-(Dicyclohexylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis(trifluoromethyl)phenyl]phosphine

(R)-1-{(RP)-2-[2-(Dicyclohexylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis(trifluoromethyl)phenyl]phosphine - CAS 494227-32-6

(R)-1-{(RP)-2-[2-(Dicyclohexylphosphino)phenyl]ferrocenyl}ethylbis[3,5-bis(trifluoromethyl)phenyl]phosphine is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

494227-32-6

CAS

494227-32-6

Synonyms

(1S)-1-[(1R)-1-[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ethyl]-2-[2-(dicyclohexylphosphino)phenyl]ferrocene (acc to CAS), Walphos SL-W008-1

Molecular Weight

942.61

Molecular Formula

C46H44F12FeP2

Product Information

Canonical SMILES

FC(F)(F)C1=CC(C(F)(F)F)=CC(P(C2=CC(C(F)(F)F)=CC(C(F)(F)F)=C2)[C@@H]([C@-]34[Fe+2]56789%10(C%11=C46[H])([C-]%12C7=C8C9=C%10%12)C%11([H])=C35C%13=C(C=CC=C%13)P(C%14CCCCC%14)C%15CCCCC%15)C)=C1

InChI

InChI=1S/C41H39F12P2.C5H5.Fe/c1-25(34-16-10-17-35(34)36-15-8-9-18-37(36)55(30-11-4-2-5-12-30)31-13-6-3-7-14-31)54(32-21-26(38(42,43)44)19-27(22-32)39(45,46)47)33-23-28(40(48,49)50)20-29(24-33)41(51,52)53;1-2-4-5-3-1;/h8-10,15-25,30-31H,2-7,11-14H2,1H3;1-5H;/t25-;;/m1../s1

InChI Key

XSNPQORPLUHYID-KHZPMNTOSA-N

MDL

MFCD04117707

Storage

Inert atmosphere. Keep cold.