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Chiral Oxygen Ligands
(R)-(+)-6,6′-dibromo-2,2′-bis(methoxymethoxy)-1,1′-binaphthalene

(R)-(+)-6,6′-dibromo-2,2′-bis(methoxymethoxy)-1,1′-binaphthalene - CAS 179866-74-1

(R)-(+)-6,6'-dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthalene is a chiral oxygen ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

179866-74-1

CAS

179866-74-1

IUPAC Name

6-bromo-1-[6-bromo-2-(methoxymethoxy)naphthalen-1-yl]-2-(methoxymethoxy)naphthalene

Synonyms

(R)-(+)-6,6′ -dibromo-2,2′ -bis(methoxymethoxy)-1,1′ -binaphthalene; (R)-(+)-6,6'-Dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthalene; (R)-(+)-6,6'-Dibromo-2,2'-bis-(methoxymethoxy)-1,1'-binaphthyl

Application

An intermediate in the symmetric synthesis of BINOL-terpyridine ligands.

Molecular Weight

532.22

Molecular Formula

C24H20Br2O4

Product Information

Canonical SMILES

COCOC1=CC=C2C=C(Br)C=CC2=C1C3=C4C=CC(Br)=CC4=CC=C3OCOC

InChI

InChI=1S/C24H20Br2O4/c1-27-13-29-21-9-3-15-11-17(25)5-7-19(15)23(21)24-20-8-6-18(26)12-16(20)4-10-22(24)30-14-28-2/h3-12H,13-14H2,1-2H3

InChI Key

UPLLZDVWXACTEG-UHFFFAOYSA-N

Purity

97%

MDL

MFCD03788936

Physical State

Solid

Appearance

Powder or Crystals

Storage

Inert atmosphere. Room Temperature.

Boiling Point

553.0±50.0 °C / 760 mmHg

Melting Point

135 °C

Density

1.524 g/cm3

Optical Activity

22° (c=1 in chloroform)

Hazard Class

Packing Groups

III

Safety Information

Signal Word

Danger

Precautionary Statement

P273 - P280 - P305+P351+P338 - P310 - P501

Hazard Statements

H318 - H413

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration _(start) × Volume _(start) = Concentration _(final) × Volume _(final)

This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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(R)-(+)-6,6′-dibromo-2,2′-bis(methoxymethoxy)-1,1′-binaphthalene - CAS 179866-74-1

Product Information

Safety Information

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