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Chiral N-Triflyl Phosphoramides
(R)-N-(2,6-Di([1,1':3',1''-terphenyl]-5'-yl)-4-oxido-7a,8,9,10,11,11a,12,13,14,15-decahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-1,1,1-trifluoromethanesulfonamide

(R)-N-(2,6-Di([1,1':3',1''-terphenyl]-5'-yl)-4-oxido-7a,8,9,10,11,11a,12,13,14,15-decahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-1,1,1-trifluoromethanesulfonamide - CAS 2152685-54-4

As a strong chiral Brønsted acid, (R)-N-(2,6-Di([1,1':3',1''-terphenyl]-5'-yl)-4-oxido-7a,8,9,10,11,11a,12,13,14,15-decahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-1,1,1-trifluoromethanesulfonamide is a chiral N-triflyl phosphoramides organocatalysts for enantioselective synthesis.

Catalog Number

2152685-54-4

CAS

2152685-54-4

Molecular Weight

946.02

Molecular Formula

C57H47F3NO5PS

Product Information

Canonical SMILES

O=P1(OC2=C(C=C3CCCCC3=C2C4=C(C(C5=CC(C6=CC=CC=C6)=CC(C7=CC=CC=C7)=C5)=CC8C4CCCC8)O1)C9=CC(C%10=CC=CC=C%10)=CC(C%11=CC=CC=C%11)=C9)NS(C(F)(F)F)(=O)=O

Storage

Inert atmosphere. Keep cold.

Safety Information

Signal Word

Warning

Precautionary Statement

P261 - P280 - P301+P312 - P302+P352 - P305+P351+P338

Hazard Statements

H302 - H315 - H319 - H335

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The dilution calculator equation

Concentration _(start) × Volume _(start) = Concentration _(final) × Volume _(final)

This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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(R)-N-(2,6-Di([1,1':3',1''-terphenyl]-5'-yl)-4-oxido-7a,8,9,10,11,11a,12,13,14,15-decahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-1,1,1-trifluoromethanesulfonamide - CAS 2152685-54-4

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