(R)-[(RuCl(H8-BINAP))2(-Cl)3][NH2Me2] - CAS 204933-84-6

(R)-[(RuCl(H8-BINAP))2(-Cl)3][NH2Me2] is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

204933-84-6

CAS

204933-84-6

IUPAC Name

[1-(2-diphenylphosphanyl-5,6,7,8-tetrahydronaphthalen-1-yl)-5,6,7,8-tetrahydronaphthalen-2-yl]-diphenylphosphane;N-methylmethanamine;ruthenium;trichloronioruthenium(1-);chloride;hydrochloride

Synonyms

Dimethylammonium dichlorotri(-chloro)bis[(R)-(+)-2,2-bis(diphenylphosphino)-5,5,6,6,7,7,8,8-octahydro-1,1-binaphthyl]diruthenate(II)

Molecular Weight

1686.97

Molecular Formula

(CH3)2NH2+[C88H80Cl5P4Ru2]−

Product Information

Canonical SMILES

Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.C3CCc4c(C3)ccc(P(c5ccccc5)c6ccccc6)c4-c7c(ccc8CCCCc78)P(c9ccccc9)c%10ccccc%10.C%11CCc%12c(C%11)ccc(P(c%13ccccc%13)c%14ccccc%14)c%12-c%15c(ccc%16CCCCc%15%16)P(c%17ccccc%17)c%18ccccc%18

InChI

InChI=1S/2C44H40P2.C2H7N.5ClH.2Ru/c2*1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-3-2;;;;;;;/h2*1-12,19-26,29-32H,13-18,27-28H2;3H,1-2H3;5*1H;;/q;;;;;;;;;+2/p-1

InChI Key

GTOHIFITHYJFSD-UHFFFAOYSA-M

MDL

MFCD09753036

Physical State

Solid

Appearance

Powder

Storage

Keep cold.

WGK Germany

The molarity calculator equation