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Chiral Phosphine Ligands
(RP,RP)-1,1-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2-bis[(S)--(dimethylamino)benzyl]ferrocene

(RP,RP)-1,1-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2-bis[(S)--(dimethylamino)benzyl]ferrocene - CAS 849925-12-8

(RP,RP)-1,1-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2-bis[(S)--(dimethylamino)benzyl]ferrocene is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

849925-12-8

CAS

849925-12-8

IUPAC Name

(1S)-1-[2-bis(4-methoxy-3,5-dimethylphenyl)phosphanylcyclopenta-1,4-dien-1-yl]-N,N-dimethyl-1-phenylmethanamine;iron(2+)

Synonyms

(1S,1S)- 1,1-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2-bis[(S)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS), Mandyphos SL-M004-2

Molecular Weight

1053.08

Molecular Formula

C64H74FeN2O4P2

Product Information

Canonical SMILES

[H]C12=C3[Fe+2]14567([C-]2(P(C8=CC(C)=C(OC)C(C)=C8)C9=CC(C)=C(OC)C(C)=C9)C4([C@H](C%10=CC=CC=C%10)N(C)C)=C53[H])(C%11=C%126[C@H](C%13=CC=CC=C%13)N(C)C)(C%11([H])=C%147[H])[C-]%12%14P(C%15=CC(C)=C(OC)C(C)=C%15)C%16=CC(C)=C(OC)C(C)=C%16

InChI

InChI=1S/2C32H37NO2P.Fe/c2*1-21-17-26(18-22(2)31(21)34-7)36(27-19-23(3)32(35-8)24(4)20-27)29-16-12-15-28(29)30(33(5)6)25-13-10-9-11-14-25;/h2*9-20,30H,1-8H3;/q2*-1;+2/t2*30-;/m00./s1

InChI Key

HPUIPHVXVUIUDU-RELFUISISA-N

MDL

MFCD08561145

Storage

Inert atmosphere. Keep cold.