RuCl2[(R)DMBINAP][(R)DAIPEN] - CAS 220114-32-9

RuCl2[(R)DMBINAP][(R)DAIPEN] is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

220114-32-9

CAS

220114-32-9

IUPAC Name

[1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane;(2R)-1,1-bis(4-methoxyphenyl)-3-methylbutane-1,2-diamine;dichlororuthenium

Synonyms

Dichloro[(R)2,2bis[di(3,5xylyl)phosphino]1,1binaphthyl][(2R)1,1bis(4methoxyphenyl)3methyl1,2butanediamine]ruthenium(II)

Molecular Weight

1221.28

Molecular Formula

C71H74Cl2N2O2P2Ru

Product Information

Canonical SMILES

COc1ccc(cc1)C2([NH2][Ru]3(Cl)(Cl)([NH2][C@@H]2C(C)C)[PH](c4cc(C)cc(C)c4)(c5cc(C)cc(C)c5)c6ccc7ccccc7c6-c8c(ccc9ccccc89)[PH]3(c%10cc(C)cc(C)c%10)c%11cc(C)cc(C)c%11)c%12ccc(OC)cc%12

InChI

InChI=1S/C52H48P2.C19H26N2O2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-13(2)18(20)19(21,14-5-9-16(22-3)10-6-14)15-7-11-17(23-4)12-8-15;;;/h9-32H,1-8H3;5-13,18H,20-21H2,1-4H3;2*1H;/q;;;;+2/p-2/t;18-;;;/m.1.../s1

InChI Key

UTQCNMRDWASSEC-OEGAAENXSA-L

MDL

MFCD09753026

Physical State

Solid

Appearance

Powder or Crystals

Storage

Inert atmosphere. Keep cold.

WGK Germany

The molarity calculator equation