RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN] - CAS 220114-03-4

RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN] is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

220114-03-4

CAS

220114-03-4

IUPAC Name

[1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane;dichlororuthenium;(1S,2S)-1,2-diphenylethane-1,2-diamine

Synonyms

Dichloro[(S)-()-2,2-bis[di(3,5-xylyl)phosphino]-1,1-binaphthyl][(1S,2S)-()-1,2-diphenylethylenediamine]ruthenium(II)

Molecular Weight

1119.15

Molecular Formula

C66H64Cl2N2P2Ru

Product Information

Canonical SMILES

Cl[Ru]Cl.N[C@H]([C@@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10

InChI

InChI=1S/C52H48P2.C14H16N2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h9-32H,1-8H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.0.../s1

InChI Key

HYMSONXJNGZZBM-LISIALKWSA-L

MDL

MFCD09753030

Physical State

Solid

Appearance

Powder or Crystals

Storage

Inert atmosphere. Keep cold.

WGK Germany

The molarity calculator equation