(S)-2,2'-Diamino-1,1'-binaphthalene - CAS 18531-95-8

Inquiry

(S)-2,2'-Diamino-1,1'-binaphthalene (CAS# 18531-95-8) is a useful research chemical.

Catalog Number

18531-95-8

CAS

18531-95-8

IUPAC Name

1-(2-aminonaphthalen-1-yl)naphthalen-2-amine

Synonyms

1-(2-amino-1-naphthalenyl)-2-naphthalenamine; 1-(2-aminonaphthalen-1-yl)naphthalen-2-amine

Molecular Weight

284.35

Molecular Formula

C20H16N2

Product Information

Canonical SMILES

C1=CC=C2C(=C1)C=CC(=C2C3=C(C=CC4=CC=CC=C43)N)N

InChI

InChI=1S/C20H16N2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12H,21-22H2

InChI Key

DDAPSNKEOHDLKB-UHFFFAOYSA-N

Purity

99 %

MDL

MFCD00145204

Physical State

Solid

Appearance

Powder

Storage

Room temperature.

Boiling Point

480.8 ℃ / 760 mmHg

Melting Point

244 ℃

Density

1.25 g/cm³

Optical Activity

-152° (c=1 in pyridine)

Hazard Class

6.1

TSCA

WGK Germany

Packing Groups

III

Safety Information

Signal Word

Danger

Precautionary Statement

P264, P270, P280, P301+P312, P305+P351+P338, P310, P330, and P501

Hazard Statements

H315 - H319 - H335

Reference Reading

1. The interaction of r(+)- or s(-)-2,2'-diamino-1,1'-binaphthalene with a pd/silica catalyst in tetrahydrofuran.

G E Robinson, G Webb, N C Young, S D Jackson. Enantiomer. 2000 Dec; 5(6): 567-70. PMID: 11342292.

The interaction of 2,2'-diamino-1,1'-binaphthalene over a Pd/silica catalyst and its interaction with hydrogen in the system and with the solvent tetrahydrofuran, (THF) has been investigated. Three interactions have been identified, i) conversion of amine groups to hydroxy groups, ii) hydrogenation of one or more of the aromatic rings, and iii) reaction between the amine group(s) and the THF solvent.

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

Mass