(S)-3,3-Di-9-anthracenyl-1,1-bi-2-naphthol - CAS 361342-50-9

(S)-3,3-Di-9-anthracenyl-1,1-bi-2-naphthol is a chiral oxygen ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

361342-50-9

CAS

361342-50-9

IUPAC Name

3-anthracen-9-yl-1-(3-anthracen-9-yl-2-hydroxynaphthalen-1-yl)naphthalen-2-ol

Synonyms

3-anthracen-9-yl-1-(3-anthracen-9-yl-2-hydroxynaphthalen-1-yl)naphthalen-2-ol;(S)-3,3'-DI(ANTHRACEN-9-YL)-1,1'-BINAPHTHYL-2,2'-DIOL;361342-49-6;361342-50-9;SCHEMBL7098784;CTK8B4077

Molecular Weight

638.75

Molecular Formula

C48H30O2

Product Information

Canonical SMILES

C1=CC=C2C(=C1)C=C3C=CC=CC3=C2C4=CC5=CC=CC=C5C(=C4O)C6=C(C(=CC7=CC=CC=C76)C8=C9C=CC=CC9=CC1=CC=CC=C18)O

InChI

InChI=1S/C48H30O2/c49-47-41(43-35-19-7-1-13-29(35)25-30-14-2-8-20-36(30)43)27-33-17-5-11-23-39(33)45(47)46-40-24-12-6-18-34(40)28-42(48(46)50)44-37-21-9-3-15-31(37)26-32-16-4-10-22-38(32)44/h1-28,49-50H

InChI Key

XJKZPSCYLJRHEN-UHFFFAOYSA-N

Purity

95%

MDL

MFCD09027270

Storage

Sealed in dry. Keep cold.

Melting Point

239-242 °C

WGK Germany

Safety Information

Signal Word

Warning

Precautionary Statement

P261 - P305 - P351 - P338

Hazard Statements

H315 - H319 - H335

Reference Reading

1.Efficient Determination of the Enantiomeric Purity and Absolute Configuration of Flavanones by Using (S)-3,3'-Dibromo-1,1'-bi-2-naphthol as a Chiral Solvating Agent.

Du G1,2, Li Y2,3, Ma S1, Wang R1, Li B2, Guo F1, Zhu W2, Li Y1. J Nat Prod. 2015 Dec 24;78(12):2968-74. doi: 10.1021/acs.jnatprod.5b00690. Epub 2015 Dec 7.

The enantiomeric purity and absolute configuration of flavanones were first determined using (S)-3,3'-dibromo-1,1'-bi-2-naphthol as a chiral solvating agent by means of (1)H NMR spectroscopy. The enantiomeric purity results closely matched those based on chiral HPLC analysis.

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

Mass