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Chiral Phosphine Ligands
(S)-(6,6-Dimethoxybiphenyl-2,2-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine]

(S)-(6,6-Dimethoxybiphenyl-2,2-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine] - CAS 927396-01-8

(S)-(6,6-Dimethoxybiphenyl-2,2-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine] is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

927396-01-8

CAS

927396-01-8

IUPAC Name

[2-[2-bis(3,4,5-trimethoxyphenyl)phosphanyl-6-methoxyphenyl]-3-methoxyphenyl]-bis(3,4,5-trimethoxyphenyl)phosphane

Synonyms

(S)-2,2-Bis[bis(3,4,5-trimethoxyphenyl)phosphino]-6,6-dimethoxy-1,1-biphenyl, (S)-3,4,5-MeO-MeOBIPHEP, SL-A104-2

Molecular Weight

942.92

Molecular Formula

C50H56O14P2

Product Information

Canonical SMILES

COC1=C(C2=C(OC)C=CC=C2P(C3=CC(OC)=C(OC)C(OC)=C3)C4=CC(OC)=C(OC)C(OC)=C4)C(P(C5=CC(OC)=C(OC)C(OC)=C5)C6=CC(OC)=C(OC)C(OC)=C6)=CC=C1

InChI

InChI=1S/C50H56O14P2/c1-51-33-17-15-19-43(65(29-21-35(53-3)47(61-11)36(22-29)54-4)30-23-37(55-5)48(62-12)38(24-30)56-6)45(33)46-34(52-2)18-16-20-44(46)66(31-25-39(57-7)49(63-13)40(26-31)58-8)32-27-41(59-9)50(64-14)42(28-32)60-10/h15-28H,1-14H3

InChI Key

JZCMGMXFWZWFRX-UHFFFAOYSA-N

Storage

Inert atmosphere. Keep cold.

Boiling Point

883.4 + / - 65.0 °C / 760 mmHg