(S)-BINAPINE - CAS 528854-26-4

(S)-BINAPINE is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

528854-26-4

CAS

528854-26-4

IUPAC Name

(12S)-13-tert-butyl-12-[(12S)-13-tert-butyl-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-12-yl]-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene

Synonyms

(3S,3' S,4S,4' S,11bS,11' bS)-(+)-4,4-Di-t-butyl-4,4,5,5-tetrahydro-3,3-bi-3H-dinaphtho[2,1-c:1,2-e]phosphepin

Molecular Weight

734.89

Molecular Formula

C52H48P2

Product Information

Canonical SMILES

CC(C)(C)P1CC2=C(C3=CC=CC=C3C=C2)C4=C(C1C5C6=C(C7=CC=CC=C7C=C6)C8=C(CP5C(C)(C)C)C=CC9=CC=CC=C98)C=CC1=CC=CC=C14

InChI

InChI=1S/C52H48P2/c1-51(2,3)53-31-37-25-23-33-15-7-11-19-39(33)45(37)47-41-21-13-9-17-35(41)27-29-43(47)49(53)50-44-30-28-36-18-10-14-22-42(36)48(44)46-38(32-54(50)52(4,5)6)26-24-34-16-8-12-20-40(34)46/h7-30,49-50H,31-32H2,1-6H3/t49-,50-,53?,54?/m0/s1

InChI Key

YXMFQIWDFKIXGQ-KUSQLHRJSA-N