(S)-RuCl[(p-cymene)(T-BINAP)]Cl - CAS 228120-95-4

(S)-RuCl[(p-cymene)(T-BINAP)]Cl is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

228120-95-4

CAS

228120-95-4

IUPAC Name

[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane;dichlororuthenium;1-methyl-4-propan-2-ylbenzene

Synonyms

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene) Ruthenium(II) chloride; [RuCl(p-cymene)((S)-tolbinap)]Cl; Ruthenium(1+), [1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-bis(4-methylphenyl)phosphine-κP]]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-, chloride (1:1); Ruthenium(1+), [(1S)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)phosphine-κP]]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-, chloride; Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride

Application

Transition Metal Catalysts

Molecular Weight

984.97

Molecular Formula

C58H54Cl2P2Ru

Product Information

Canonical SMILES

[Cl-].[Cl-][Ru+2]123456([CH]=7[CH]5=C4(C(C)C)[CH]3=[CH]2C71C)[P](C8=CC=C(C=C8)C)(C9=CC=C(C=C9)C)C%10=CC=C%11C=CC=CC%11=C%10C=%12C=%13C=CC=CC%13C=CC%12[P]6(C%14=CC=C(C=C%14)C)C%15=CC=C(C=C%15)C

InChI

InChI=1S/C48H40P2.C10H14.2ClH.Ru/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;1-8(2)10-6-4-9(3)5-7-10;;;/h5-32H,1-4H3;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChI Key

BHIUOOHVIWKUTN-UHFFFAOYSA-L

Purity

≥95%

MDL

MFCD09753014

Physical State

Solid

Appearance

Light Yellow to Brown Crystal

Storage

Store at 2-8°C

Melting Point

>100°C

WGK Germany

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Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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(S)-RuCl[(p-cymene)(T-BINAP)]Cl - CAS 228120-95-4

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