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(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene

(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene - CAS 1221745-90-9

(SP)-1-[(R)-tert-Butylphosphinoyl]-2-[(R)-1-(diphenylphosphino)ethyl]ferrocene is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

1221745-90-9

CAS

1221745-90-9

IUPAC Name

(Z)-tert-butyl-[2-[(1S)-1-diphenylphosphanylethyl]cyclopenta-2,4-dien-1-ylidene]-oxidophosphanium;cyclopenta-1,3-diene;iron(2+)

Synonyms

(1R)-1-[(R)-(1,1-Dimethylethyl)phosphinyl]-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS), JoSPOphos SL-J681-1

Molecular Weight

502.35

Molecular Formula

C28H31FeOP2+

Product Information

Canonical SMILES

CC(C1=CC=CC1=[P+](C(C)(C)C)[O-])P(C2=CC=CC=C2)C3=CC=CC=C3.[CH-]1C=CC=C1.[Fe+2]

InChI

InChI=1S/C23H26OP2.C5H5.Fe/c1-18(21-16-11-17-22(21)26(24)23(2,3)4)25(19-12-7-5-8-13-19)20-14-9-6-10-15-20;1-2-4-5-3-1;/h5-18H,1-4H3;1-5H;/q;-1;+2/t18-;;/m1../s1

InChI Key

GKGAXSFACFRVDP-JPKZNVRTSA-N

Purity

95%

Storage

Inert atmosphere. Keep cold.

WGK Germany