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Chiral Phosphine Ligands
(SP,SP)-1,1-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2-bis[(R)--(dimethylamino)benzyl]ferrocene

(SP,SP)-1,1-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2-bis[(R)--(dimethylamino)benzyl]ferrocene - CAS 494227-36-0

(SP,SP)-1,1-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2-bis[(R)--(dimethylamino)benzyl]ferrocene is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

494227-36-0

CAS

494227-36-0

Synonyms

(1R,1R)-1,1-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2-bis[(R)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS), Mandyphos SL-M003-1

Molecular Weight

1364.74

Molecular Formula

C60H42F24FeN2P2

Product Information

Canonical SMILES

[Fe].CN(C)[C@@H]([C]1[CH][CH][CH][C]1P(c2cc(cc(c2)C(F)(F)F)C(F)(F)F)c3cc(cc(c3)C(F)(F)F)C(F)(F)F)c4ccccc4.CN(C)[C@@H]([C]5[CH][CH][CH][C]5P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F)c8ccccc8

InChI

InChI=1S/2C30H21F12NP.Fe/c2*1-43(2)26(17-7-4-3-5-8-17)24-9-6-10-25(24)44(22-13-18(27(31,32)33)11-19(14-22)28(34,35)36)23-15-20(29(37,38)39)12-21(16-23)30(40,41)42;/h2*3-16,26H,1-2H3;/t2*26-;/m11./s1

InChI Key

PYLZWHGISWCHOW-PMIUFOJNSA-N

Purity

≥97%

MDL

MFCD04117703

Storage

Inert atmosphere. Keep cold.

WGK Germany

Safety Information

Signal Word

Warning

Precautionary Statement

P261 - P280 - P301+P312 - P302+P352 - P305+P351+P338

Hazard Statements

H302 - H315 - H319 - H335

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This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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(SP,SP)-1,1-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2-bis[(R)--(dimethylamino)benzyl]ferrocene - CAS 494227-36-0

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