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Chiral Phosphine Ligands
(-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

(-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE - CAS 528565-84-6

(-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

528565-84-6

CAS

528565-84-6

IUPAC Name

(1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-[2-[(2R,5R)-2,5-diphenylphospholan-1-yl]ethyl]-2,5-diphenylphospholane;rhodium;tetrafluoroborate

Synonyms

(-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE; (R,R)-PH-BPE-RH; (-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(R,R)-Ph-BPE-Rh

Molecular Weight

804.49

Molecular Formula

C42H48BF4P2Rh

Product Information

Canonical SMILES

[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2C[C@@H](P(CCP3[C@H](CC[C@@H]3c4ccccc4)c5ccccc5)[C@H]2c6ccccc6)c7ccccc7

InChI

InChI=1S/C34H36P2.C8H12.BF4.Rh/c1-5-13-27(14-6-1)31-21-22-32(28-15-7-2-8-16-28)35(31)25-26-36-33(29-17-9-3-10-18-29)23-24-34(36)30-19-11-4-12-20-30;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-20,31-34H,21-26H2;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t31-,32-,33-,34-;;;/m1.../s1

InChI Key

ZNZBTPZGQIGMKZ-FMUQXVHFSA-N

MDL

MFCD07369037

Physical State

Solid

Appearance

Orange to brown powder

WGK Germany

Safety Information

Signal Word

Warning

Precautionary Statement

P302+P352 - P305+P351+P338

Hazard Statements

H315 - H319 - H335

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration _(start) × Volume _(start) = Concentration _(final) × Volume _(final)

This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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(-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE - CAS 528565-84-6

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