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(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooCtadiene)rhodium(I) tetrafluoroborate

(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooCtadiene)rhodium(I) tetrafluoroborate - CAS 210057-23-1

(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooCtadiene)rhodium(I) tetrafluoroborate is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

210057-23-1

CAS

210057-23-1

IUPAC Name

(1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane;rhodium;tetrafluoroborate

Synonyms

(-)-1,2-BIS((2R,5R)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) BF4; (-)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE; (-)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TE

Molecular Weight

604.26

Molecular Formula

C26H40P2Rh.BF4

Product Information

Canonical SMILES

[B-](F)(F)(F)F.CC1CCC(P1C2=CC=CC=C2P3C(CCC3C)C)C.C1CC=CCCC=C1.[Rh]

InChI

InChI=1S/C18H28P2.C8H12.BF4.Rh/c1-13-9-10-14(2)19(13)17-7-5-6-8-18(17)20-15(3)11-12-16(20)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h5-8,13-16H,9-12H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/t13-,14-,15-,16-;;;/m1.../s1

InChI Key

ZUMNNKGIZSDCBZ-DBMWKRJKSA-N

Purity

95%

MDL

MFCD01862466

Appearance

Red powder

Boiling Point

415ºC at 760 mmHg

WGK Germany

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