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Chiral Phosphine Ligands
Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl

Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl - CAS 944451-24-5

Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-xylbinap}]Cl is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

944451-24-5

CAS

944451-24-5

IUPAC Name

[1-[2-bis(3,5-dimethylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(3,5-dimethylphenyl)phosphane;dichlororuthenium;1-methyl-4-propan-2-ylbenzene

Synonyms

Chloro[(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl](p-cymene)ruthenium(II) Chloride

Molecular Weight

1041.08

Molecular Formula

[C62H62ClP2Ru]+Cl-

Product Information

Canonical SMILES

[Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.Cc2cc(C)cc(c2)P(c3cc(C)cc(C)c3)c4ccc5ccccc5c4-c6c(ccc7ccccc67)P(c8cc(C)cc(C)c8)c9cc(C)cc(C)c9

InChI

InChI=1S/C52H48P2.C10H14.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-8(2)10-6-4-9(3)5-7-10;;;/h9-32H,1-8H3;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChI Key

CBZXDZCPCDMKJU-UHFFFAOYSA-L

MDL

MFCD09753015

Physical State

Solid

Appearance

Powder

Storage

Inert atmosphere. Keep cold.

WGK Germany