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Chiral Phosphine Ligands
Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium (II)

Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium (II) - CAS 212210-87-2

Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1S,2S) -(-)-1,2-diphenylethylenediamine]ruthenium (II) is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

212210-87-2

CAS

212210-87-2

IUPAC Name

dichlororuthenium;(1S,2S)-1,2-diphenylethane-1,2-diamine;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane

Synonyms

[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1S,2S)-(-)-1,2-diphenylethylenediamine] Ruthenium(II) dichloride; Ruthenium, [1,1'-(1R)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dichloro[(1S,2S)-1,2-diphenyl-1,2-ethanediamine-κN1,κN2]-, (OC-6-13)-; (OC-6-13)-[1,1'-(1R)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]dichloro[(1S,2S)-1,2-diphenyl-1,2-ethanediamine-κN1,κN2]ruthenium; Ruthenium, [(1R)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-κP]]dichloro[(1S,2S)-1,2-diphenyl-1,2-ethanediamine-κN,κN']-, (OC-6-13)-

Application

Transition Metal Catalysts

Molecular Weight

1006.96

Molecular Formula

C58H48Cl2N2P2Ru

Product Information

Canonical SMILES

[Cl-][Ru+2]12([Cl-])([NH2]C(C=3C=CC=CC3)C(C=4C=CC=CC4)[NH2]1)[P](C=5C=CC=CC5)(C=6C=CC=CC6)C7=CC=C8C=CC=CC8=C7C=9C=%10C=CC=CC%10C=CC9[P]2(C=%11C=CC=CC%11)C=%12C=CC=CC%12

InChI

InChI=1S/C44H32P2.C14H16N2.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h1-32H;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2

InChI Key

PZTVCDSGEXHVBL-UHFFFAOYSA-L

Purity

95%

MDL

MFCD02684566

Appearance

White to Pale Yellow Powder

Storage

Store at -20°C

Melting Point

>300°C