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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl] diruthenate(II)

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl] diruthenate(II) - CAS 199541-17-8

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl] diruthenate(II) is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

199541-17-8

CAS

199541-17-8

IUPAC Name

dimethylazanium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;ruthenium(2+);pentachloride

Synonyms

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II); (S)-[(RuCl(BINAP))2(μ-Cl)3][NH2Me2]; Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(I

Molecular Weight

1670.87

Molecular Formula

2C44H32P2.C2H7N.Cl.Cl3Ru2.ClH

Product Information

Canonical SMILES

Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.c3ccc(cc3)P(c4ccccc4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9ccccc9)c%10ccccc%10.c%11ccc(cc%11)P(c%12ccccc%12)c%13ccc%14ccccc%14c%13-c%15c(ccc%16ccccc%15%16)P(c%17ccccc%17)c%18ccccc%18

InChI

InChI=1S/2C44H32P2.C2H7N.5ClH.2Ru/c2*1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-3-2;;;;;;;/h2*1-32H;3H,1-2H3;5*1H;;/q;;;;;;;;2*+2/p-4

InChI Key

LFCGWRXZQGOBMD-UHFFFAOYSA-J

MDL

MFCD09753033

Physical State

Solid

Appearance

Orange to Dark Orange Powder

Storage

Keep in dark place. Inert atmosphere. Keep cold.

Hazard Class

4.1

WGK Germany

Packing Groups

III

Safety Information

Signal Word

Warning

Precautionary Statement

P210

Hazard Statements

H228

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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl] diruthenate(II) - CAS 199541-17-8

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