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Chiral Phosphine Ligands
Phosphine,1,1'-tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-diphenyl-,stereoisomer

Phosphine,1,1'-tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-diphenyl-,stereoisomer - CAS 192463-40-4

Phosphine,1,1'-tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-diphenyl-,stereoisomer is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

192463-40-4

CAS

192463-40-4

IUPAC Name

(11-diphenylphosphanyl-5-tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaenyl)-diphenylphosphane

Synonyms

(S)-(+)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE; (R)-PHANEPHOS; (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE; Bisdiphenylphosphinoparacyclophane; 4-FLUOROBENZOYLACETONITRILE, 97% N-BOC-4-OXO-L-PROLINE, 97%; (s)-phanephos; (S)-(+)-4,12-Bis(

Molecular Weight

576.65

Molecular Formula

C40H34 P2

Product Information

Canonical SMILES

P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC4=CC=C3CCC5=CC=C(CC4)C(P(C6=CC=CC=C6)C7=CC=CC=C7)=C5

InChI

InChI=1S/C40H34P2/c1-5-13-35(14-6-1)41(36-15-7-2-8-16-36)39-29-31-21-25-33(39)27-23-32-22-26-34(28-24-31)40(30-32)42(37-17-9-3-10-18-37)38-19-11-4-12-20-38/h1-22,25-26,29-30H,23-24,27-28H2

InChI Key

GYZZZILPVUYAFJ-UHFFFAOYSA-N

Purity

96%

MDL

MFCD03094575

Physical State

Solid

Appearance

White to tan solid, powder, crystals, crystalline powder

Storage

Inert atmosphere. Keep cold.

Melting Point

224-226 °C

Optical Activity

+34°( c = 1 in chloroform)

WGK Germany

Safety Information

Signal Word

Warning

Precautionary Statement

P261 - P305 - P351 - P338

Hazard Statements

H302 - H315 - H319 - H335

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration _(start) × Volume _(start) = Concentration _(final) × Volume _(final)

This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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Phosphine,1,1'-tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-diphenyl-,stereoisomer - CAS 192463-40-4

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