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Chiral Phosphine Ligands
(R)-1-[(R)-2-[2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]PHENYL]FERROCENYL]-ETHYLBIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINE

(R)-1-[(R)-2-[2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]PHENYL]FERROCENYL]-ETHYLBIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINE - CAS 494227-30-4

(R)-1-[(R)-2-[2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]PHENYL]FERROCENYL]-ETHYLBIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINE is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

494227-30-4

CAS

494227-30-4

Synonyms

(R)-1-[(R)-2-[2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]PHENYL]FERROCENYL]-ETHYLBIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINE; (R)-(+)-1-[(R)-2-(2'-DI(3,5-DIMETHYL-4-METHOXYPHENYL)PHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-TRIFLUOROMETHYLPHENYL)PHOSPHI

Molecular Weight

1046.68

Molecular Formula

C52H44F12FeO2P2 10*

Product Information

Canonical SMILES

CC1=CC(=CC(=C1OC)C)P(C2=CC=CC=C2[C]3[CH][CH][CH][C]3C(C)P(C4=CC(=CC(=C4)C(F)(F)F)C(F)(F)F)C5=CC(=CC(=C5)C(F)(F)F)C(F)(F)F)C6=CC(=C(C(=C6)C)OC)C.[CH]1[CH][CH][CH][CH]1.[Fe]

InChI

InChI=1S/C47H39F12O2P2.C5H5.Fe/c1-25-15-34(16-26(2)42(25)60-6)63(35-17-27(3)43(61-7)28(4)18-35)41-14-9-8-11-40(41)39-13-10-12-38(39)29(5)62(36-21-30(44(48,49)50)19-31(22-36)45(51,52)53)37-23-32(46(54,55)56)20-33(24-37)47(57,58)59;1-2-4-5-3-1;/h8-24,29H,1-7H3;1-5H;/t29-;;/m1../s1

InChI Key

LYSMTOMQQHQCKG-SYXKTQFYSA-N

Purity

95%

MDL

MFCD04117708

Storage

Inert atmosphere. Keep cold.

Safety Information

Signal Word

Warning

Precautionary Statement

P261 - P305+P351+P338

Hazard Statements

H302 - H315 - H319 - H335

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration _(start) × Volume _(start) = Concentration _(final) × Volume _(final)

This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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(R)-1-[(R)-2-[2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]PHENYL]FERROCENYL]-ETHYLBIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINE - CAS 494227-30-4

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