(R)-(+)-2,2-Bis(di-p-tolylphosphino)-1,1-binaphthyl - CAS 99646-28-3

(R)-T-BINAP complexes derived from rhodium precursors are used for the asymmetric hydroformylation of vinyl acetate. It may be employed as chiral catalyst for allylation of N-tosyl α-imino esters.<br/>Takasago Ligands and Complexes for Asymmetric Reactions<br/>Catalyst involved in studies of the role of excess phosphine ligand in enantioselective conjugate addition of ethylmagnesium bromide and α,β-unsaturated esterReactant serving as a precursor for: • Catalysts used for reductive amination of ketones• Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives• Chiral platinum catalysts for asymmetric Baeyer-Villiger oxidation of cyclic ketones• CuI-Tol-BINAP catalysts for enantioselective Michael reactions of Grignard reagents to unsaturated esters• BINAP Pt Dications for cation trapping

Catalog Number

BCC-01072

CAS

99646-28-3

IUPAC Name

[1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane

Synonyms

(R)-Tol-BINAP

Molecular Weight

678.78

Molecular Formula

C48H40P2