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Chiral Phosphine Ligands
(αR,αR)-1,1'-BIS[α-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE

(αR,αR)-1,1'-BIS[α-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE - CAS 494227-35-9

(αR,αR)-1,1'-BIS[α-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

494227-35-9

CAS

494227-35-9

Synonyms

MANDYPHOS SL-M002-1; (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE; (S,S)-(+)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE; (R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYL

Molecular Weight

844.95

Molecular Formula

C52H74FeN2P2 10*

Product Information

Canonical SMILES

[H]C12=C3[Fe+2]14567([C-]2(P(C8CCCCC8)C9CCCCC9)C4([C@@H](C%10=CC=CC=C%10)N(C)C)=C53[H])(C%11=C%126[C@@H](C%13=CC=CC=C%13)N(C)C)(C%11([H])=C%147[H])[C-]%12%14P(C%15CCCCC%15)C%16CCCCC%16

InChI

InChI=1S/2C26H37NP.Fe/c2*1-27(2)26(21-13-6-3-7-14-21)24-19-12-20-25(24)28(22-15-8-4-9-16-22)23-17-10-5-11-18-23;/h2*3,6-7,12-14,19-20,22-23,26H,4-5,8-11,15-18H2,1-2H3;/t2*26-;/m11./s1

InChI Key

OMHGSRQJSWIMDO-PMIUFOJNSA-N

MDL

MFCD04117702

Storage

Inert atmosphere. Keep cold.