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Chiral Phosphine Ligands
(RP,RP)-1,1-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2-bis[(S)--(dimethylamino)benzyl]ferrocene

(RP,RP)-1,1-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2-bis[(S)--(dimethylamino)benzyl]ferrocene - CAS 849925-10-6

(RP,RP)-1,1-Bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2-bis[(S)--(dimethylamino)benzyl]ferrocene is a chiral phosphine ligand for enantioselective synthesis with high yield and high enantioselective results.

Catalog Number

849925-10-6

CAS

849925-10-6

Synonyms

(1S,1S)-1,1-Bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]-2,2-bis[(S)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS), Mandyphos SL-M003-2

Molecular Weight

1364.74

Molecular Formula

C60H42F24FeN2P2

Product Information

Canonical SMILES

[H]C12=C3[Fe+2]14567([C-]2(P(C8=CC(C(F)(F)F)=CC(C(F)(F)F)=C8)C9=CC(C(F)(F)F)=CC(C(F)(F)F)=C9)C4([C@H](C%10=CC=CC=C%10)N(C)C)=C53[H])(C%11=C%126[C@H](C%13=CC=CC=C%13)N(C)C)(C%11([H])=C%147[H])[C-]%12%14P(C%15=CC(C(F)(F)F)=CC(C(F)(F)F)=C%15)C%16=CC(C(F)(F)F

InChI

InChI=1S/2C30H21F12NP.Fe/c2*1-43(2)26(17-7-4-3-5-8-17)24-9-6-10-25(24)44(22-13-18(27(31,32)33)11-19(14-22)28(34,35)36)23-15-20(29(37,38)39)12-21(16-23)30(40,41)42;/h2*3-16,26H,1-2H3;/t2*26-;/m00./s1

InChI Key

PYLZWHGISWCHOW-FKMBXMNYSA-N

MDL

MFCD08561144

Storage

Inert atmosphere. Keep cold.